Page 181 - handbook 20162017

Faculty of Science Handbook, Session 2016/2017

References:
1.P. Monk & L. J. Munro, Maths for Chemistry: A chemist Carboxylic acids and nitriles, carboxylic acid derivatives
nd
toolkit of calculation, 2 ed., Oxford University Press: and nucleophilic acyl substitution; difunctional compounds
New York, 2010. – keto acids, hydroxy acids/esters, and lactones.
nd
2.E. Steiner. The Chemistry Maths Book, 2 ed., Oxford
University Press: New York, 2008. Acidity of the -hydrogen in carbonyl compounds; enol-
3.M.C.R. Cockett & G. Doggett, Math for Chemists, Vol. I: keto tautomerism;
Numbers, Functions & Calculus, The Royal Society of Reactions which proceed via enols and enolate ions:
Chemistry: Cambridge, 2003. racemization, -halogenation of aldehydes and ketones,
4.M.C.R. Cockett & G. Doggett, Math for Chemists, Vol. II: base-catalysed halogenation (haloform reaction).
Power Series, Complex Number and Linear Algebra,
The Royal Society of Chemistry: Cambridge, 2003. Enolate ion alkylation: use of lithium enolates in alkylation,
regioselective enolate formation: kinetic and
SIC2001 INORGANIC CHEMISTRY II thermodynamic enolates; lithium enolates in alkylation of
ketones, esters, acids; alkylation of -dicarbonyl
Coordination chemistry: Coordinate bond, types of ligands, compounds for example,-acetic ester and malonic ester
coordination number, nomenclature, isomerism and synthesis; alkylation of nitriles, nitroalkanes and 1,3-
chirality, Werner's theory, valence bond theory, magnetic dithianes; alkylation of enamines.
properties, crystal field theory, ligand field theory, Jahn-
Teller effect, tetrahedral complex, octahedral complex, Enolate ion addition/condensation reactions: aldols,
tetragonal distortion, electronic spectra, Orgel diagram crossed aldol, intramolecular aldol, such as Mukaiyama
and Tanabe-Sugano diagram. aldol, Claisen, crossed Claisen, intramolecular Claisen
(Dieckmann), Knoevenagel, acylation of enamines, etc.
Molecular Symmetry: Symmetry elements, symmetry
operations, point groups, stereographic projections, group Conjugate addition of enolates, for example, Michael
theory, transformation matrices, reducible representation, addition, enamines in conjugate addition; Robinson
irreducible representation, character tables, application in annulation, Mannich reaction, etc.
IR and Raman spectroscopies and chiral molecules.
Preparation and use of silyl enol ethers, aza-enolates, and
Metal chemistry: Occurrence, methods of extraction, enamines, as enol equivalents.
chemical reactions and applications of metals, chemistry
of block d and f metals Assessment Methods:
Practical: 25%
Assessment Methods: Continuous assessment: 15%
Practical: 25% Final examination: 60%
Continuous assessment: 15%
Final examination: 60% Medium of instruction:
English
Medium of instruction:
English Soft skills:
CT2, CT3
Soft skills:
CT1-3 References:
th
1.T. W. G. Solomons, Organic Chemistry, 8 ed., Wiley,
References: 2004.
th
1. D. F. Shriver, P. W. Atkins, and C. H. Langford, 2.J. McMurry, Organic Chemistry, 5 ed. Brooks/Cole.
Inorganic Chemistry, 2 nd ed., Oxford University Press, 3.R. M. Silverstein, F. X. Webster, Spectrometric
1996. Identification of Organic Compounds, Wiley
2. F. A. Cotton & G. Wilkinson, Advanced Inorganic 4.Kamaliah Mahmood, Noorsaadah Abd. Rahman,
Chemistry, 5 ed., John Wiley, 1988. Kaedah Kimia dalam Pengenalpastian Sebatian
th
3.R. L. Carter, Molecular Symmetry and Group Theory, Organik, Penerbit Univ. Malaya.
John Wiley, 1998. 5.P. Crews, J. Rodriguez, M Jaspars, Organic Structure
4.N. N. Greenwood & A. Earnshaw, Chemistry of the Analysis, Oxford University Press, New York, Oxford,
Element, Pergamon Press, 1984. 1998.
5.G. L. Meisller & D. A. Tarr, Inorganic Chemistry, 3 ed.,
rd
Pearson Prentice Hall, 2004.
SIC2003 PHYSICAL CHEMISTRY II
SIC2002 ORGANIC CHEMISTRY II
Quantum Chemistry
Preparation and reactions of alkyl halides: nucleophilic The origin of quantum theory; Postulates and general
aliphatic substitution: S N1, S N2; and elimination reactions: principles of quantum mechanics: wavefunction, operator,
E1, E2. eigenfunction, eigenvalue, probability, average value and
Schrodinger equation; Dynamic and motion of simple
Preparation and reactions of alcohols (hydroboration, microscopic systems: translational motion, harmonic
oxymercuration-demercuration, etc.), phenols, aryl halides oscillator and vibrational motion, angular momentum and
and nucleophilic aromatic substitution, ethers and rotational motion; Electronic structures of hydrogen like
epoxides, thiols and sulfides; atoms and many-electron atoms: hydrogen atom, atomic
orbital, Pauli principle, aufbau principle, Hund's rules,
Use of organometallic reagents (RLi, RMgX, R 2CuLi) in electron configuration, Slater determinant, angular
synthesis amines and nitrogen-containing compounds. momentum coupling, atomic terms, spin-orbit and other
interactions, symmetry, atomic spectra and selection rules.
Carbonyl chemistry: preparation and reactions of
aldehyde and ketones, nucleophilic addition at carbonyl
carbon;

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