Page 182 - handbook 20162017

Faculty of Science Handbook, Session 2016/2017
Chemical Kinetics
Complex reactions. Collision between molecules, gas Equilibria
Important equilibria in analytical chemistry, acid-base
transport phenomenom. Collsion theory of uni, bi and equilibria, calculating pH of buffer solutions, acid-base
trimolecular gas reactions. Introduction to reaction rate titration curves.
theory.
Chemical Thermodynamics Complexometric titrations and metal speciation
Metal complex equilibria, EDTA – the ligand and its
Second law of thermodynamics. Thermodynamic complexes, selectivity via control of pH, selectivity via
properties of multi component mixtures. Equilibrium of masking agent, applications of EDTA.
chemical reactions. Phase equilibrium: phase transition
and classification; phase rule, phase diagram for multi Assessment Methods:
component system (liquid-vapour, liquid-liquid and liquid- Practical: 30%
solid) and applications. Continuous assessment: 20%
Final examination: 50%
Assessment Methods:
Practical: 25% Medium of instruction:
Continuous assessment: 15% English
Final examination: 60%
Soft skills:
Medium of instruction: CT1-3
English
References:
Soft skills: 1.D. A. Skoog, D. M. West, F.J. Holler & S.R Crouch,
CT1-3 Fundamentals of Analytical Chemistry, 9 ed., Cengage,
th
Brooks/ Cole, 2014.
References: 2.Francis Rouessac & Annick Roussac, Chemical
1.P. W. Atkins, Physical Chemistry, 9 th ed., Oxford Analysis-Modern Instrumental Methods and Techniques,
University Press, 2010. 2 ed., John Wiley & Sons, 2007.
nd
2.Donald A. McQuarrie, Quantum Chemistry, University 3.G. D. Christian, Analytical Chemistry, 7 ed., John Wiley
th
Science Book, 1983
& Son, 2014.
3.F. J. Bockhoff, Elements of Quantum Theory, 2 nd ed., 4.D. L. Robert, Aqueous acid-base equilibria and titrations,
Addison-Wesley Pub. Company, 1976. Oxford: Oxford University Press, 1999.
4.G. M. Barrow, Physical Chemistry, 6 ed., McGraw-Hill, 5.S. Gerold, Complexometric titrations, London : Methuen,
th
1996. 1969.
5.R. A. Alberty & R. J. Silbey, Physical Chemistry, 2 ed., 6.I.S. Krull, Trace metal analysis and speciation,
th
John Wiley, 1997. Amsterdam : Elsevier, 1991.
SIC2004 ANALYTICAL CHEMISTRY I SIC2005 POLYMER CHEMISTRY I
Introduction Fundamental polymer chemistry
Classical analysis, concentration systems / units, sampling Classification and naming. Processes of polymer
in analysis. synthesis: bulk, solution, suspension and emulsion.
Mechanisms of polymerization: condensation, Carothers
Data Treatment Equations, radical, ionic (cationic and anionic).
Precision and accuracy, statistical methods for error Copolymerization: structures and properties of
analysis, population and sampling, confidence limits, copolymers, reactivity ratios. Thermosets: fenoplast,
measurement uncertainty, significant figures, test for aminoplast, unsaturated polyesters, polyurethanes epoxy
mean, rejection of analytical data. Quality control and resins. Relationship between structure and properties:
quality assurance. structural isomers, stereospecific vinyl polymers, and
structures of polymers from diene monomers and ways to
Spectrometry overcome or reduce the problems of environmental
Interaction of light energy between atoms and molecules; pollutions.
quantitative aspects of absorption. Molecular
spectrometric techniques – UV-Visible, IR, NIR; Physical chemistry of polymers
dispersion, absorption, fluorescence and emission. Simple kinetic of radical polymerization. Introduction to the
Spectrophotometric instruments; emission spectroscopy size and conformation of polymer chain. Polymer in
and atomic absorption spectrometry- an introduction, uses solution– interaction between solvent and polymer
of spectrophotometry. molecules. Effect of molecular weight on the physical
properties of polymers. Distribution of molecular weights
Electroanalytical Chemistry and average molecular weights M n and M v. Determination
Quantitative analysis – standard addition technique and of average molecular weight: (a) end-group analysis, (b)
internal standard technique, Potentiometry – pH glass osmometry, (c) viscometry.
electrode, solid membrane ion selective electrodes.
Heyrovsky equation. Assessment Methods:
Practical: 30%
Separation Methods Continuous assessment: 20%
Introduction to the theory and process of separation in GC Final examination: 50%
and HPLC, ion exchange chromatography, solvent
extraction, partition coefficient, multiple extraction, Medium of instruction:
efficiency. English
Soft skills:
CT1-3

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