Page 177 - tmp

Faculty of Science Handbook, Session 2017/2018

4.M.C.R. Cockett & G. Doggett, Math for Chemists, Vol. II: Reactions which proceed via enols and enolate ions:
Power Series, Complex Number and Linear Algebra, racemization, -halogenation of aldehydes and ketones,
The Royal Society of Chemistry: Cambridge, 2003. base-catalysed halogenation (haloform reaction).
Enolate ion alkylation: use of lithium enolates in alkylation,
SIC2001 INORGANIC CHEMISTRY II regioselective enolate formation: kinetic and
thermodynamic enolates; lithium enolates in alkylation of
Coordination chemistry: Coordinate bond, types of ligands, ketones, esters, acids; alkylation of -dicarbonyl
coordination number, nomenclature, isomerism and compounds for example,-acetic ester and malonic ester
chirality, Werner's theory, valence bond theory, magnetic synthesis; alkylation of nitriles, nitroalkanes and 1,3-
properties, crystal field theory, ligand field theory, Jahn- dithianes; alkylation of enamines.
Teller effect, tetrahedral complex, octahedral complex,
tetragonal distortion, electronic spectra, Orgel diagram Enolate ion addition/condensation reactions: aldols,
and Tanabe-Sugano diagram. crossed aldol, intramolecular aldol, such as Mukaiyama
aldol, Claisen, crossed Claisen, intramolecular Claisen
Molecular Symmetry: Symmetry elements, symmetry (Dieckmann), Knoevenagel, acylation of enamines, etc.
operations, point groups, stereographic projections, group
theory, transformation matrices, reducible representation, Conjugate addition of enolates, for example, Michael
irreducible representation, character tables, application in addition, enamines in conjugate addition; Robinson
IR and Raman spectroscopies and chiral molecules. annulation, Mannich reaction, etc.
Metal chemistry: Occurrence, methods of extraction, Preparation and use of silyl enol ethers, aza-enolates, and
chemical reactions and applications of metals, chemistry enamines, as enol equivalents.
of block d and f metals
Assessment Methods:
Assessment Methods: Practical: 25%
Practical: 25% Continuous assessment: 15%
Continuous assessment: 15% Final examination: 60%
Final examination: 60%
Medium of instruction:
Medium of instruction: English
English
Soft skills:
Soft skills: CT2, CT3
CT1-3
References:
th
References: 1.T. W. G. Solomons, Organic Chemistry, 8 ed., Wiley,
1. D. F. Shriver, P. W. Atkins, and C. H. Langford, 2004. th
Inorganic Chemistry, 2 nd ed., Oxford University Press, 2.J. McMurry, Organic Chemistry, 5 ed. Brooks/Cole.
1996. 3.R. M. Silverstein, F. X. Webster, Spectrometric
2. F. A. Cotton & G. Wilkinson, Advanced Inorganic Identification of Organic Compounds, Wiley
Chemistry, 5 ed., John Wiley, 1988. 4.Kamaliah Mahmood, Noorsaadah Abd. Rahman,
th
3.R. L. Carter, Molecular Symmetry and Group Theory, Kaedah Kimia dalam Pengenalpastian Sebatian
John Wiley, 1998. Organik, Penerbit Univ. Malaya.
4.N. N. Greenwood & A. Earnshaw, Chemistry of the 5.P. Crews, J. Rodriguez, M Jaspars, Organic Structure
Element, Pergamon Press, 1984. Analysis, Oxford University Press, New York, Oxford,
5.G. L. Meisller & D. A. Tarr, Inorganic Chemistry, 3 ed., 1998.
rd
Pearson Prentice Hall, 2004.
SIC2003 PHYSICAL CHEMISTRY II
SIC2002 ORGANIC CHEMISTRY II
Quantum Chemistry
Preparation and reactions of alkyl halides: nucleophilic
aliphatic substitution: S N1, S N2; and elimination reactions: The origin of quantum theory; Postulates and general
E1, E2. principles of quantum mechanics: wavefunction, operator,
eigenfunction, eigenvalue, probability, average value and
Preparation and reactions of alcohols (hydroboration, Schrodinger equation; Dynamic and motion of simple
oxymercuration-demercuration, etc.), phenols, aryl halides microscopic systems: translational motion, harmonic
and nucleophilic aromatic substitution, ethers and oscillator and vibrational motion, angular momentum and
epoxides, thiols and sulfides; rotational motion; Electronic structures of hydrogen like
atoms and many-electron atoms: hydrogen atom, atomic
Use of organometallic reagents (RLi, RMgX, R 2CuLi) in orbital, Pauli principle, aufbau principle, Hund's rules,
synthesis amines and nitrogen-containing compounds. electron configuration, Slater determinant, angular
momentum coupling, atomic terms, spin-orbit and other
Carbonyl chemistry: preparation and reactions of interactions, symmetry, atomic spectra and selection rules.
aldehyde and ketones, nucleophilic addition at carbonyl Chemical Kinetics
carbon;
Complex reactions. Collision between molecules, gas
Carboxylic acids and nitriles, carboxylic acid derivatives transport phenomenom. Collsion theory of uni, bi and
and nucleophilic acyl substitution; difunctional compounds trimolecular gas reactions. Introduction to reaction rate
– keto acids, hydroxy acids/esters, and lactones. theory.
Chemical Thermodynamics
Acidity of the -hydrogen in carbonyl compounds; enol-
keto tautomerism; Second law of thermodynamics. Thermodynamic
properties of multi component mixtures. Equilibrium of

173