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Faculty of Science Handbook, Session 2017/2018

chemical reactions. Phase equilibrium: phase transition Assessment Methods:
and classification; phase rule, phase diagram for multi Practical: 30%
component system (liquid-vapour, liquid-liquid and liquid- Continuous assessment: 20%
solid) and applications. Final examination: 50%
Assessment Methods: Medium of instruction:
Practical: 25% English
Continuous assessment: 15%
Final examination: 60% Soft skills:
CT1-3
Medium of instruction:
English References:
1.D. A. Skoog, D. M. West, F.J. Holler & S.R Crouch,
th
Soft skills: Fundamentals of Analytical Chemistry, 9 ed., Cengage,
CT1-3 Brooks/ Cole, 2014.
2.Francis Rouessac & Annick Roussac, Chemical
References: Analysis-Modern Instrumental Methods and Techniques,
1.P. W. Atkins, Physical Chemistry, 9 th ed., Oxford 2 ed., John Wiley & Sons, 2007.
nd
University Press, 2010. 3.G. D. Christian, Analytical Chemistry, 7 ed., John Wiley
th
2.Donald A. McQuarrie, Quantum Chemistry, University & Son, 2014.
Science Book, 1983 4.D. L. Robert, Aqueous acid-base equilibria and titrations,
3.F. J. Bockhoff, Elements of Quantum Theory, 2 nd ed., Oxford: Oxford University Press, 1999.
Addison-Wesley Pub. Company, 1976. 5.S. Gerold, Complexometric titrations, London : Methuen,
4.G. M. Barrow, Physical Chemistry, 6 ed., McGraw-Hill, 1969.
th
1996. 6.I.S. Krull, Trace metal analysis and speciation,
th
5.R. A. Alberty & R. J. Silbey, Physical Chemistry, 2 ed., Amsterdam : Elsevier, 1991.
John Wiley, 1997.
SIC2005 POLYMER CHEMISTRY I
SIC2004 ANALYTICAL CHEMISTRY I
Fundamental polymer chemistry
Introduction Classification and naming. Processes of polymer
Classical analysis, concentration systems / units, sampling synthesis: bulk, solution, suspension and emulsion.
in analysis. Mechanisms of polymerization: condensation, Carothers
Equations, radical, ionic (cationic and anionic).
Data Treatment Copolymerization: structures and properties of
Precision and accuracy, statistical methods for error copolymers, reactivity ratios. Thermosets: fenoplast,
analysis, population and sampling, confidence limits, aminoplast, unsaturated polyesters, polyurethanes epoxy
measurement uncertainty, significant figures, test for resins. Relationship between structure and properties:
mean, rejection of analytical data. Quality control and structural isomers, stereospecific vinyl polymers, and
quality assurance. structures of polymers from diene monomers and ways to
overcome or reduce the problems of environmental
Spectrometry pollutions.
Interaction of light energy between atoms and molecules;
quantitative aspects of absorption. Molecular Physical chemistry of polymers
spectrometric techniques – UV-Visible, IR, NIR; Simple kinetic of radical polymerization. Introduction to the
dispersion, absorption, fluorescence and emission. size and conformation of polymer chain. Polymer in
Spectrophotometric instruments; emission spectroscopy solution– interaction between solvent and polymer
and atomic absorption spectrometry- an introduction, uses molecules. Effect of molecular weight on the physical
of spectrophotometry. properties of polymers. Distribution of molecular weights
and average molecular weights M n and M v. Determination
Electroanalytical Chemistry of average molecular weight: (a) end-group analysis, (b)
Quantitative analysis – standard addition technique and osmometry, (c) viscometry.
internal standard technique, Potentiometry – pH glass
electrode, solid membrane ion selective electrodes. Assessment Methods:
Heyrovsky equation. Practical: 30%
Continuous assessment: 20%
Separation Methods Final examination: 50%
Introduction to the theory and process of separation in GC
and HPLC, ion exchange chromatography, solvent Medium of instruction:
extraction, partition coefficient, multiple extraction, English
efficiency.
Soft skills:
Equilibria CT1-3
Important equilibria in analytical chemistry, acid-base
equilibria, calculating pH of buffer solutions, acid-base References:
nd
titration curves. 1.Joel R. Fried, Polymer Science and Technology, 2 ed.,
Prentice Hall International Editions, 2003.
Complexometric titrations and metal speciation 2.R. A, Harry & W. L. Frederick, Contemporary Polymer
Metal complex equilibria, EDTA – the ligand and its Chemistry, 2 ed., Prentice Hall, 1992.
nd
complexes, selectivity via control of pH, selectivity via 3.M. P. Steven, Polymer Chemistry – An Introduction, 3 rd
masking agent, applications of EDTA. ed., Oxford Univ. Press, 1999.
4.G. Challa, Polymer Chemistry - an Introduction, Ellis
Horwood, 1993.

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