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spectroscopy. Introduction of Raman effect. Electronic organometallics (carbonyl, hydride, alkyl/alkene, carbene, carbyne,
spectroscopy of atoms and molecules; electronic term symbols for metallocene & fullerene) organometallic reactions.
atoms and molecules. Introduction of photoelectron spectroscopy.
Basics of diatomic and polyatomic molecular electronic Metal chemistry:
spectroscopy. Magnetic nuclei in an external magnetic field. FT Occurrence, methods of extraction, chemical reactions and
NMR experiments. Boltzman distribution and population of energy applications of metals, chemistry of block d and f metals.
levels. Relaxation processes and width of spectral lines. High
resolution NMR spectra: chemical shift and spin-spin coupling. Assessment Weightage:
First-order and second-order spectrum. Exchange processes. Continuous assessment: 40%
Double resonance experiments. NMR spectra of solids. Final examination: 60%

Assessment Weightage:
Continuous assessment: 40% SIC3021 PRACTICAL OF INORGANIC CHEMISTRY III
Final examination: 60%
Synthesis of organometallic compounds, spectroscopic analysis for
structural determination and investigation of point group based on
SIC2024 SPECTROSCOPIC METHODS IN ORGANIC IR and Raman spectra.
CHEMISTRY
Assessment Weightage:
IR spectroscopy: Characteristic functional group absorptions in Continuous assessment: 100%
organic molecules. Final examination: -

UV spectroscopy: electronic transitions and common
chromophores in organic compounds; Beer-Lambert Law and SIC3022 ORGANIC CHEMISTRY III
Woodward-Fieser Rules. Correlation between optical spectra and
MO theory. Strategies in multistep synthesis: retrosynthetic analysis. Synthesis
NMR spectroscopy: 1H-NMR – chemical shift: inductive and of C-C-bonds.
anisotropic effects; Spin-spin coupling: geminal and vicinal
coupling, Karplus equation; examples of 1H-1H splitting patterns; Asymmetric synthesis: axial chirality, importance of enantiopure
allylic and long-range coupling; techniques for improving the NMR compounds, chiral pool; selected examples of asymmetric
spectrum: use of shift reagents. 13C NMR spectrum – e.g., synthesis including hydrogenation, epoxidation, dihydroxylation,
completely-coupled, completely- decoupled; off-resonance- use of chiral auxiliaries.
decoupled; APT and DEPT spectra; carbon chemical shifts and
functional groups. Reactivity; intermediates and product studies, energetics and
kinetics, isotope effects and linear free energy relationships.
Mass spectrometry: EIMS – molecular ions, isotope peaks,
fragmentation ions and patterns. HREIMS and determination of Assessment Weightage:
molecular formula of organic compounds. Application of combined Continuous assessment: 40%
techniques in organic structure determination. Final examination: 60%

Assessment Weightage:
Continuous assessment: 40%
Final examination: 60% SIC3023 PRACTICAL OF ORGANIC CHEMISTRY III

‘Oligo-step’ organic synthesis; Carbonyl chemistry: Correlation of
experimental operations with theory;
SIC2025 CHEMISTRY AND SOCIETY
Separation of organic compounds using an acid-base extraction
This course exposes students to community services and scheme; application of qualitative elemental analysis, functional
volunteerism with the knowledge of chemistry to assist the group tests, spectroscopy and small- scale chemical conversion for
community in solving current issues. the identification of organic compounds.

Students need to plan and implement programs in groups, as well Assessment Weightage:
as group reports and presentations based on experiences with the Continuous assessment: 100%
communities. Final examination: -

Assessment Weightage:
Continuous assessment: 100% SIC3024 PHYSICAL CHEMISTRY III
Final examination: -
Part A: Electronic Structure Theory and Photochemistry
Linear variational method, Time independent and dependent
SIC3020 INORGANIC CHEMISTRY III perturbation theories, Angular momentum theory. Energy diagram
of many-electron atoms, Molecular orbital theory and electronic
Organometallic Chemistry: potential energy.
Historical background, classification/bonding types of
organometallics compounds of transition elements, main group Absorption and emission of light, Fluorescence and quenching,
organometallics & lanthanides, 18-electron rules, ligands in Intramolecular vibrational energy redistribution, Internal conversion,
Intersystem crossing, Phosphorescence, Photodissociation, Laser-