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SIC3021 PRACTICAL OF INORGANIC
CHEMISTRY III References:
Synthesis of organometallic compounds, 1. Williamson, K. L., & Masters, K. M. (2010).
spectroscopic analysis for structural determination Macroscale and microscale organic experiments.
and investigation of point group based on IR and Cengage Learning.
Raman spectra. 2. Furniss, B. S. (1989). Vogel's textbook of practical
organic chemistry. Pearson Education India.
Assessment Weightage
Continuous assessment 100%
SIC3024 PHYSICAL CHEMISTRY III
References:
1. E. Housecroft and A. G. Sharpe, Inorganic Part A: Electronic Structure Theory and
Chemistry, 5th edn., Pearson Prentice Hall, 2018. Photochemistry. Linear variational method, time-
2. M. Weller, T. Overton and J. Rourke, Inorganic independent and time-dependent perturbation
Chemistry, 7th edn, Oxford University Press, 2018. theories, angular momentum theory. Energy
3. J. E. House and K. A. House, Descriptive Inorganic diagrams of many-electron atoms, molecular
Chemistry, 3rd edn., Academic Press, 2015. orbital theory, and electronic potential energy.
Absorption and emission of light, Fluorescence and
quenching, Intramolecular vibrational energy
SIC3022 ORGANIC CHEMISTRY III redistribution, Internal conversion, Intersystem
crossing, Phosphorescence, Photodissociation,
Strategies in multistep synthesis: retrosynthetic Laser-induced fluorescence, Multiphoton
analysis. Synthesis of C-C-bonds. Asymmetric ionization, Photochemistry on short time scales,
synthesis: axial chirality, importance of enantiopure Atmospheric chemistry.
compounds, chiral pool; selected examples of
asymmetric synthesis including hydrogenation, Part B: Statistical Thermodynamics and Dynamics
epoxidation, dihydroxylation, use of chiral of Molecular Reactions.
auxiliaries. Reactivity; intermediates and product The fundamentals of statistical mechanics from the
studies, energetics and kinetics, isotope effects definitions of molecular interactions giving a set of
and linear free energy relationships. energy levels for N-molecule systems. Statistical
treatment to obtain a distribution of the most
Assessment Weightage probable energy configuration or Boltzmann
Continuous assessment 40% distribution. Introduction to partition function of
Summative assessment 60% molecules containing all the information on N-
molecule systems. Ensemble concept,
References: incorporated partition function and its relation to
1. Jonathan Clayden, Nick Greeves, Stuart Warren, thermodynamic properties. Diffusion controlled
Peter Wothers, Organic Chemistry, 2th Edition, reactions. Activated complex theory and reactions
Oxford Press, 2012 (latest edition). in solutions. The dynamics of molecular collisions.
2. Michael Smith, Organic Synthesis, 4th Edition,
Academic Press, 2016. Assessment Weightage
3. David E, Lewis, Advanced Organic Chemistry, Continuous assessment 40%
23rd Edition (Dewey), Oxford Uni. Press (New Summative assessment 60%
York), 2016.
4. S. Warren, Organic Synthesis, Disconnection References:
Approach, John Wiley & Sons Inc., 2019
1. P. W. Atkins, Physical Chemistry, 11th ed., Oxford
University Press, New York, 2018.
SIC3023 PRACTICAL OF ORGANIC 2. P. W. Atkins, Molecular Quantum Mechanics, 5th
CHEMISTRY III ed., Oxford University Press, New York, 2011.
3. J. P. Lowe, Quantum Chemistry, 3rd ed., Academic
‘Oligo-step’ organic synthesis; Carbonyl chemistry: Press, New York, 2011.
Correlation of experimental operations with theory; 4. P. W., Atkins, J. de Paula, Physical Chemistry for
Separation of organic compounds using an acid- the Life Sciences, 2nd ed., Oxford University
base extraction scheme; application of qualitative Press, New York, 2011.
elemental analysis, functional group tests,
spectroscopy and small- scale chemical
conversion for the identification of organic SIC3025 PRACTICAL OF PHYSICAL
compounds CHEMISTRY III
Assessment Weightage Bomb calorimetry, molecular spectroscopy, the
Continuous assessment 100% critical point, determination of acid dissociation
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