Page 172 - buku panduan 20192020

Faculty of Science Handbook, Session 2019/2020

SIC2001 INORGANIC CHEMISTRY II thermodynamic enolates; lithium enolates in alkylation of
ketones, esters, acids; alkylation of -dicarbonyl
Coordination chemistry: Coordinate bond, types of ligands, compounds for example acetic ester and malonic ester
coordination number, nomenclature, isomerism and synthesis; alkylation of nitriles, nitroalkanes and 1,3-
chirality, Werner's theory, valence bond theory, magnetic dithianes; alkylation of enamines.
properties, crystal field theory, ligand field theory, Jahn-
Teller effect, tetrahedral complex, octahedral complex, Enolate ion addition/condensation reactions: aldols,
tetragonal distortion, electronic spectra, Orgel diagram crossed aldol, intramolecular aldol, such as Mukaiyama
and Tanabe-Sugano diagram. aldol, Claisen, crossed Claisen, intramolecular Claisen
(Dieckmann), Knoevenagel, acylation of enamines, etc.
Molecular Symmetry: Symmetry elements, symmetry
operations, point groups, stereographic projections, group Conjugate addition of enolates, for example, Michael
theory, transformation matrices, reducible representation, addition, enamines in conjugate addition; Robinson
irreducible representation, character tables, application in annulation, Mannich reaction, etc.
IR and Raman spectroscopies and chiral molecules.
Preparation and use of silyl enol ethers, aza-enolates, and
Metal chemistry: Occurrence, methods of extraction, enamines, as enol equivalents.
chemical reactions and applications of metals, chemistry
of block d and f metals Assessment Methods:
Practical: 25%
Assessment Methods: Continuous assessment: 15%
Practical: 25% Final examination: 60%
Continuous assessment: 15%
Final examination: 60% Medium of instruction:
English
Medium of instruction:
English Soft skills:
CT2, CT3
Soft skills:
CT1-3 References:
1. T. W. G. Solomons, Organic Chemistry, 8 ed., Wiley,
th
References: 2004.
1. D. F. Shriver, P. W. Atkins, and C. H. Langford, 2. J. McMurry, Organic Chemistry, 5 ed. Brooks/Cole.
th
nd
Inorganic Chemistry, 2 ed., Oxford University Press, 3. R. M. Silverstein, F. X. Webster, Spectrometric
1996. Identification of Organic Compounds, Wiley
2. F. A. Cotton & G. Wilkinson, Advanced Inorganic 4. Kamaliah Mahmood, Noorsaadah Abd. Rahman,
th
Chemistry, 5 ed., John Wiley, 1988. Kaedah Kimia dalam Pengenalpastian Sebatian
3. R. L. Carter, Molecular Symmetry and Group Theory, Organik, Penerbit Univ. Malaya.
John Wiley, 1998. 5. P. Crews, J. Rodriguez, M Jaspars, Organic Structure
4. N. N. Greenwood & A. Earnshaw, Chemistry of the Analysis, Oxford University Press, New York, Oxford,
Element, Pergamon Press, 1984. 1998.
rd
5. G. L. Meisller & D. A. Tarr, Inorganic Chemistry, 3 ed.,
Pearson Prentice Hall, 2004.
SIC2003 PHYSICAL CHEMISTRY II

SIC2002 ORGANIC CHEMISTRY II Quantum Chemistry
The origin of quantum theory; Postulates and general
Preparation and reactions of alkyl halides: nucleophilic principles of quantum mechanics: wavefunction, operator,
aliphatic substitution: S N1, S N2; and elimination reactions: eigenfunction, eigenvalue, probability, average value and
E1, E2. Schrodinger equation; Dynamic and motion of simple
microscopic systems: translational motion, harmonic
Preparation and reactions of alcohols (hydroboration, oscillator and vibrational motion, angular momentum and
oxymercuration-demercuration, etc.), phenols, aryl halides rotational motion; Electronic structures of hydrogen like
and nucleophilic aromatic substitution, ethers and atoms and many-electron atoms: hydrogen atom, atomic
epoxides, thiols and sulfides; orbital, Pauli principle, aufbau principle, Hund's rules,
electron configuration, Slater determinant, angular
Use of organometallic reagents (RLi, RMgX, R 2CuLi) in momentum coupling, atomic terms, spin-orbit and other
synthesis amines and nitrogen-containing compounds. interactions, symmetry, atomic spectra and selection rules.

Carbonyl chemistry: preparation and reactions of Chemical Kinetics
aldehyde and ketones, nucleophilic addition at carbonyl Complex reactions. Collision between molecules, gas
carbon; transport phenomenom. Collsion theory of uni, bi and
trimolecular gas reactions. Introduction to reaction rate
Carboxylic acids and nitriles, carboxylic acid derivatives theory.
and nucleophilic acyl substitution; difunctional compounds
– keto acids, hydroxy acids/esters, and lactones. Chemical Thermodynamics
Second law of thermodynamics. Thermodynamic
Acidity of the -hydrogen in carbonyl compounds; enol- properties of multi component mixtures. Equilibrium of
keto tautomerism; chemical reactions. Phase equilibrium: phase transition
Reactions which proceed via enols and enolate ions: and classification; phase rule, phase diagram for multi
racemization, -halogenation of aldehydes and ketones, component system (liquid-vapour, liquid-liquid and liquid-
base-catalysed halogenation (haloform reaction). solid) and applications.

Enolate ion alkylation: use of lithium enolates in alkylation,
regioselective enolate formation: kinetic and

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