Page 109 - Handbook Bachelor Degree of Science Academic Session 20212022

Faculty of Science Handbook, Academic Session 2021/2022

Assessment Weightage:
Assessment Weightage: Continuous assessment: 100%
Continuous assessment: 40% Final examination: -
Final examination: 60%
References:
References: 1. Williamson, K. L., & Masters, K. M. (2010). Macroscale
1. E. Housecroft and A. G. Sharpe, Inorganic Chemistry, and microscale organic experiments. Cengage
5th edn., Pearson Prentice Hall, 2018. Learning.
2. M. Weller, T. Overton and J. Rourke, Inorganic 2. Furniss, B. S. (1989). Vogel's textbook of practical
Chemistry, 7th edn, Oxford University Press, 2018. organic chemistry. Pearson Education India.
3. J. E. House and K. A. House, Descriptive Inorganic
Chemistry, 3rd edn., Academic Press, 2015.
SIC3024 PHYSICAL CHEMISTRY III

SIC3021 PRACTICAL OF INORGANIC CHEMISTRY III Part A: Electronic Structure Theory and
Photochemistry
Synthesis of organometallic compounds, spectroscopic Linear variational method, Time independent and
analysis for structural determination and investigation of dependent perturbation theories, Angular momentum
point group based on IR and Raman spectra. theory. Energy diagram of many-electron atoms, Molecular
orbital theory and electronic potential energy.
Assessment Weightage:
Continuous assessment: 100% Absorption and emission of light, Fluorescence and
Final examination: - quenching, Intramolecular vibrational energy redistribution,
Internal conversion, Intersystem crossing,
References: Phosphorescence, Photodissociation, Laser-induced
1. E. Housecroft and A. G. Sharpe, Inorganic Chemistry, fluorescence, Multiphoton ionization, Photochemistry on
th
5 edn., Pearson Prentice Hall, 2018. short time scales, Atmospheric chemistry.
2. M. Weller, T. Overton and J. Rourke, Inorganic
th
Chemistry, 7 edn, Oxford University Press, 2018. Part B: Statistical Thermodynamics and Dynamics of
3. J. E. House and K. A. House, Descriptive Inorganic Molecular Reactions
Chemistry, 3rd edn., Academic Press, 2015. The fundamentals of statistical mechanics from the
definitions of molecular interactions giving a set of energy
levels for N-molecule systems. Statistical treatment to
SIC3022 ORGANIC CHEMISTRY III obtain a distribution of the most probable energy
configuration or Boltzmann distribution. Introduction to
Strategies in multistep synthesis: retrosynthetic analysis. partition function of molecules containing all the information
Synthesis of C-C-bonds. on N-molecule systems. Ensemble concept, incorporated
partition function and its relation to thermodynamic
Asymmetric synthesis: axial chirality, importance of properties.
enantiopure compounds, chiral pool; selected examples of
asymmetric synthesis including hydrogenation, Diffusion controlled reactions. Activated complex theory and
epoxidation, dihydroxylation, use of chiral auxiliaries. reactions in solutions. The dynamics of molecular collisions.

Reactivity; intermediates and product studies, energetics Assessment Weightage:
and kinetics, isotope effects and linear free energy Continuous assessment: 40%
relationships. Final examination: 60%

Assessment Weightage: References:
th
Continuous assessment: 40% 1.P. W. Atkins, Physical Chemistry, 11 ed., Oxford
Final examination: 60% University Press, New York, 2018
th
2.P. W. Atkins, Molecular Quantum Mechanics, 5 ed.,
References: Oxford University Press, New York, 2011.
rd
1. Jonathan Clayden, Nick Greeves, Stuart Warren, Peter 3.J. P. Lowe, Quantum Chemistry, 3 ed., Academic Press,
Wothers, Organic Chemistry, 2th Edition, Oxford Press, New York, 2011.
2012 (latest edition) 4.P. W., Atkins, J. de Paula, Physical Chemistry for the Life
2. Michael Smith, Organic Synthesis, 4th Edition, Sciences, 2 ed., Oxford University Press, New York,
nd
Academic Press, 2016 2011.
3. David E, Lewis, Advanced Organic Chemistry, 23rd
Edition (Dewey), Oxford Uni. Press (New York), 2016
4. S. Warren, Organic Synthesis, Disconnection SIC3025 PRACTICAL OF PHYSICAL CHEMISTRY III
Approach, John Wiley & Sons Inc., 2019
Bomb calorimetry, molecular spectroscopy, the critical
point, determination of acid dissociation constant for methyl
SIC3023 PRACTICAL OF ORGANIC CHEMISTRY III red, phase diagram of a three-component partially
immiscible liquid system, hydrolysis of tert-butyl chloride,
‘Oligo-step’ organic synthesis; Carbonyl chemistry: influence of alcohol chain elongation on the surface activity
Correlation of experimental operations with theory; for normal aliphatic alcohol, determination of vapour
viscosity, rotational-vibrational spectra of HCl and DCl.
Separation of organic compounds using an acid-base
extraction scheme; application of qualitative elemental Assessment Weightage:
analysis, functional group tests, spectroscopy and small- Continuous assessment: 100%
scale chemical conversion for the identification of organic Final examination: -
compounds

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